Previous: 2.12 Maxwell's Relations
The rules of partial differentiation
Identify the independent variables, eg
and
.
If
, the partial derivative of
with respect to
is obtained by holding
constant;
it is written
It follows that
The order of differentiation doesn't matter:
The change in
as a result of changes in
and
is
 |
(2.1) |
We could take
and
to be the independent variables, with
.
Now the partial derivatives are
Note the first is no longer required to be zero - it's
, not
, that is held constant. In this case,
 |
(2.2) |
By comparing (2.1) and (2.2) with
, we see that
 |
(2.3) |
From (2.1) we have
 |
(2.4) |
In the second line, ``dividing
by
'' gave
, not
, because the first line was only true for constant
.
Rearranging (2.4) also gives
 |
(2.5) |
The minus sign in these is counter-intuitive.
Equations (2.3), (2.4) and (2.5) are our main results, and may be new to you.
References
Previous: 2.12 Maxwell's Relations
Judith McGovern
2004-03-17