Previous: 2.12 Maxwell's Relations
The rules of partial differentiation
Identify the independent variables, eg and .
If , the partial derivative of with respect to is obtained by holding constant;
it is written
It follows that
The order of differentiation doesn't matter:
The change in as a result of changes in and is
|
(2.1) |
We could take and to be the independent variables, with .
Now the partial derivatives are
Note the first is no longer required to be zero - it's , not , that is held constant. In this case,
|
(2.2) |
By comparing (2.1) and (2.2) with , we see that
|
(2.3) |
From (2.1) we have
|
(2.4) |
In the second line, ``dividing by '' gave
, not
, because the first line was only true for constant .
Rearranging (2.4) also gives
|
(2.5) |
The minus sign in these is counter-intuitive.
Equations (2.3), (2.4) and (2.5) are our main results, and may be new to you.
References
Previous: 2.12 Maxwell's Relations
Judith McGovern
2004-03-17